Hildebrand solubility parameter for the solvent-solute pair are close G noncomb will be small and S comb will assure that G mix will be less than zero. Hildebrandt solubility parameter works well for non-polar species without hydrogen bondings. For such species Hansen solubility parameters can be used.
Hansen solubility parameters were developed by Charles M. Hansen in his Ph.D thesis in 1967 as a way of predicting if one material will dissolve in another and form a solution. They are based on the idea that like dissolves like where one molecule is defined as being ‘like’ another if it bonds to itself in a similar way. The solubility parameters can be determined by the measurement of the solubility, similar to the Hildebrand parameters. Several solvents are chosen and trials of the solubility of a substance with unknown Hansen solubility parameters are done. Another method of access of the solubility parameters is by inverse gas chromatography .
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Solubility Parameter Furfuryl Alcoho